Dicumyl peroxide → HCID 131713083, compound

HRID 1995421Notes

Reaction equation

HRID 1995421 reaction equation
[CH3:1][N:2]1[C:7]([CH3:9])([CH3:8])[CH2:6][CH:5]([O:10][C:11](=[O:29])[C:12]([CH2:14][C:15]([O:17][CH:18]2[CH2:23][C:22]([CH3:25])([CH3:24])[N:21]([CH3:26])[C:20]([CH3:28])([CH3:27])[CH2:19]2)=[O:16])=[CH2:13])[CH2:4][C:3]1([CH3:31])[CH3:30].[CH3:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH:40]=[CH2:41].C(OOC(C1C=CC=CC=1)(C)C)(C1C=CC=CC=1)(C)C>C1(C)C=CC=CC=1>[CH3:1][N:2]1[C:7]([CH3:9])([CH3:8])[CH2:6][CH:5]([O:10][C:11](=[O:29])[C:12]([CH2:14][C:15]([O:17][CH:18]2[CH2:23][C:22]([CH3:25])([CH3:24])[N:21]([CH3:26])[C:20]([CH3:28])([CH3:27])[CH2:19]2)=[O:16])=[CH2:13])[CH2:4][C:3]1([CH3:31])[CH3:30].[CH3:41][CH2:40][CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][CH:33]=[CH2:32]

Participants

5

Reactant 3

HCID 6641Dicumyl peroxideHCID 133811-DeceneHCID 54002279HCID 54002279, compound

Product 1

HCID 131713083HCID 131713083, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Conditions

Temperature
150 °C

Procedure

Bis(1,2,2,6,6-pentamethyl-4-piperidyl)itaconate 2.6 g (6 mmole), decene-1 0.6 g (4.3 mmole) and dicumyl peroxide 0.05 g were dissolved in 14 ml of toluene and heated and stirred at 150° C. for seven hours. The solvent was distilled off, and a pale yellow solid was obtained.

Workup

  1. temperatureheated
  2. distillationThe solvent was distilled off
  3. customa pale yellow solid was obtained

Sources & evidence

ORD record
ord-5e339ec9b72a4335baa9b1edd32c9bf1
Source dataset
uspto-grants-1983_09
Patent number
US04404301

Reaction notes

Loading…