Hydrochloric Acid → HCID 131711741, compound

HRID 2049541Notes

Reaction equation

HRID 2049541 reaction equation
[N:1]([O-])=O.[Na+].[CH3:5][C:6]1[CH:19]=[CH:18][C:9]([S:10][C:11]2[CH:17]=[CH:16][C:14]([NH2:15])=[CH:13][CH:12]=2)=[CH:8][CH:7]=1.[ClH:20]>O.C(O)(=O)C>[Cl-:20].[CH3:5][C:6]1[CH:19]=[CH:18][C:9]([S:10][C:11]2[CH:17]=[CH:16][C:14]([N+:15]#[N:1])=[CH:13][CH:12]=2)=[CH:8][CH:7]=1

Participants

6

Reactant 3

HCID 313Hydrochloric AcidHCID 4593764-[(4-methylphenyl)sulfanyl]anilineHCID 23668193Sodium Nitrite

Product 1

HCID 131711741HCID 131711741, compound

Reagents, catalysts & solvents 2

HCID 176Acetic AcidSolventHCID 962WaterSolvent

Procedure

A solution of 2.8 g (0.04 mol) of sodium nitrite in 15 ml of water is added dropwise, at an internal temperature of max. 10° C., to 10.7 g (0.04 mol) of 4-(4-methylthiophenoxy)-aniline in 100 ml of glacial acetic acid and 7.5 ml of conc. hydrochloric acid. Then stirring is continued for 15 minutes.

Workup

  1. custom10° C.

Sources & evidence

ORD record
ord-54f6a8d5244e46adbbfc772a4b2f3662
Source dataset
uspto-grants-1980_04
Patent number
US04198407

Reaction notes

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