Diethylamine → HCID 86736494, compound

HRID 2049985Notes

Reaction equation

HRID 2049985 reaction equation
[C:1]([O:4][CH2:5]/[C:6](/[CH2:16][CH2:17]/[CH:18]=[C:19](\[CH3:26])/[CH2:20][CH2:21][CH:22]=[C:23]([CH3:25])[CH3:24])=[CH:7]/[CH2:8][CH2:9]/[C:10](/[CH3:15])=[CH:11]/[C:12]([OH:14])=O)(=[O:3])[CH3:2].C(Cl)(=O)C(Cl)=O.[CH2:33]([NH:35][CH2:36][CH3:37])[CH3:34]>>[CH2:33]([N:35]([CH2:36][CH3:37])[C:12](=[O:14])/[CH:11]=[C:10](\[CH3:15])/[CH2:9][CH2:8]/[CH:7]=[C:6](/[CH2:5][O:4][C:1](=[O:3])[CH3:2])\[CH2:16][CH2:17]/[CH:18]=[C:19](\[CH3:26])/[CH2:20][CH2:21][CH:22]=[C:23]([CH3:25])[CH3:24])[CH3:34]

Participants

4

Reactant 3

HCID 8021DiethylamineHCID 65578Oxalyl chlorideHCID 86736495(E,E,E)-7-acetoxymethyl-3,11,15-trimethyl-2,6,10,14-hexadecatetraenoic acid

Product 1

HCID 86736494HCID 86736494, compound

Procedure

Following the same manner as in Example 12, 1.0 g of (E,Z,E) and (E,E,E)-7-acetoxymethyl-3,11,15-trimethyl-2,6,10,14-hexadecatetraenoic acid was converted to the corresponding acid chloride with 1.5 ml of oxalyl chloride and the reaction with 1.0 ml of diethylamine afforded 820 mg of the end product.

Sources & evidence

ORD record
ord-190ea36b8d3c4ad39c4f655789fc807c
Source dataset
uspto-grants-1980_04
Patent number
US04199519

Reaction notes

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