Methanol → 1-Methoxy-2-dodecanol

HRID 2050417Notes

Reaction equation

[O:1]1[CH:3]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH2:2]1.[Na].[CH3:15][OH:16]>>[CH3:15][O:16][CH2:2][CH:3]([OH:1])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]

Participants

Reactant 3

HCID 887Methanol

HCID 178581,2-Epoxydodecane

HCID 5360545Sodium

Product 1

HCID 137094341-Methoxy-2-dodecanolYield 88%

Procedure

1,2-Epoxydodecane is reacted with sodium in methanol as in Example 1 to yield 1-methoxy-2-dodecanol as a colourless oil, bp 97° C./0.07 mbar, yield 88%.

Sources & evidence

ORD record: ord-0fa2527294c9415f8f6c23c6aa9dac8b
Source dataset: uspto-grants-1991_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05013482

Reaction notes

Loading…