Hydrogen Peroxide → N,N-didodecylhydroxylamine

HRID 2050424Notes

Reaction equation

HRID 2050424 reaction equation
[CH2:1]([NH:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[OH:26]O>C(O)CC>[CH2:14]([N:13]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])[OH:26])[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 18157Didodecylamine

Product 1

HCID 9864141N,N-didodecylhydroxylamine

Reagents, catalysts & solvents 1

HCID 10311-PropanolSolvent

Procedure

Following the general procedure of Example 5, to a solution of 50 grams (0.14 mol) of didodecylamine dissolved in 200 ml of n-propanol at 40° C. is added dropwise 9.62 grams (0.14 mol) of 50% aqueous hydrogen peroxide solution. After 72 hours at 40-45° C., the reaction mixture is filtered to give a crude product which is subsequently recrystallized from 300 ml of hexane. The above-named product is obtained in a yield of 24.8 grams (48%) as white needles melting at 90-92° C.

Workup

  1. filtrationthe reaction mixture is filtered
  2. customto give a crude product which
  3. customis subsequently recrystallized from 300 ml of hexane

Sources & evidence

ORD record
ord-fcb0fd2e5dec4b0eade07cf8bfb8931a
Source dataset
uspto-grants-1991_05
Patent number
US05013510

Reaction notes

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