Allylamine → HCID 54354084, compound

HRID 2051827Notes

Reaction equation

HRID 2051827 reaction equation
O=[CH:2][C@@H:3]([C@H:5]([C@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4].[CH2:13]([NH2:16])[CH:14]=[CH2:15].[Cl:17][CH2:18][CH2:19][N:20]=[C:21]=[O:22]>>[Cl:17][CH2:18][CH2:19][NH:20][C:21]([N:16]([CH2:13][CH:14]=[CH2:15])[CH:2]1[O:10][C@H:9]([CH2:11][OH:12])[C@H:7]([OH:8])[C@H:5]([OH:6])[C@H:3]1[OH:4])=[O:22]

Participants

4

Reactant 3

HCID 7853AllylamineHCID 160352-Chloroethyl isocyanateHCID 3037556(2R,3S,4S,5R)-2,3,4,5,6-pentahydroxyhexanal

Product 1

HCID 54354084HCID 54354084, compoundYield 66.3%

Procedure

3.6 g of D-galactose, 1.5 g of 2-propenylamine and 2.5 g of 2-chloroethyl isocyanate are treated in the same manner as described in Example 5-(1). 4.3 g of 1-(2-chloroethyl)-3-(2-propenyl)-3-D-galactopyranosylurea are obtained as colorless caramel. IRνmaxnujol (cm-1): 3400, 1640, 1535, 1070

Sources & evidence

ORD record
ord-0d4f9878e32c4d85b970af3b7b63a2a4
Source dataset
uspto-grants-1980_01
Patent number
US04182757

Reaction notes

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