Phenylhydrazine → 3-[(2-Phenylhydrazinylidene)methyl]pyridine

HRID 2057745Notes

Reaction equation

HRID 2057745 reaction equation
[N:1]1[CH:6]=[CH:5][CH:4]=[C:3]([CH:7]=O)[CH:2]=1.[C:9]1([NH:15][NH2:16])[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1>C(O)C>[C:9]1([NH:15][N:16]=[CH:7][C:3]2[CH:2]=[N:1][CH:6]=[CH:5][CH:4]=2)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1

Participants

4

Reactant 2

HCID 7516PhenylhydrazineHCID 103713-Pyridinecarboxaldehyde

Product 1

HCID 2587553-[(2-Phenylhydrazinylidene)methyl]pyridine

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

10.8 g of 3-pyridinecarbaldehyde was dissolved in 30 ml of ethanol. 10.8 g of phenylhydrazine was added to the stirred solution, at room temperature. 3 crystallized out as yellow prisms, mp 158-160.5° C.

Workup

  1. custom3 crystallized out as yellow prisms, mp 158-160.5° C.

Sources & evidence

ORD record
ord-dcbdb97167494c3fa22d1bec4273dc61
Source dataset
uspto-grants-1980_07
Patent number
US04212868

Reaction notes

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