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HRID2058690

反应详情

EQUATION

反应方程式

HRID 2058690 的结构方程式

REACTANTS

反应物

3
反应SMILES：CC=O
HCID177

Acetaldehyde

C2H4O

反应SMILES：CC(C)[N-]C(C)C.[Li+]
HCID2724682

2-Propanamine, N-(1-methylethyl)-, lithium salt

C6H14LiN

反应SMILES：[N-]=[N+]=NCCOC1=C(C(=O)OCc2ccccc2)N2C(=O)CC2C1
HCID15136300

未命名化合物

PRODUCTS

产物

1
反应SMILES：CC(O)C1C(=O)N2C(C(=O)OCc3ccccc3)=C(OCCN=[N+]=[N-])CC12
HCID20549299

未命名化合物

PROCEDURE

实验过程

Benzyl 3-(2-azidoethyloxy)-1-azabicyclo[3.2.0]hept-2-en-7-one-2-carboxylate is reacted with lithium diisopropylamide and acetaldehyde as described in Example 19 to provide benzyl 6-(1-hydroxyethyl)-3-(2-azidoethyloxy)-1-azabicyclo[3.2.0]hept-2-en-7-one-2-carboxylate.