Dichloromethane → HCID 13035114, compound

HRID 2059342Notes

Reaction equation

HRID 2059342 reaction equation
C([O-])(O)=O.[Na+].CCCCCCC.C(Cl)Cl.Cl.[CH2:17]([O:21][C:22](=[O:31])[CH2:23][NH:24][C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)[CH2:18][CH2:19][CH3:20]>O>[CH2:17]([O:21][C:22](=[O:31])[CH2:23][NH:24][C:25]1[CH:26]=[CH:27][CH:28]=[CH:29][CH:30]=1)[CH2:18][CH2:19][CH3:20]

Participants

6

Reactant 4

HCID 6344DichloromethaneHCID 8900HeptaneHCID 516892Sodium BicarbonateHCID 13035115HCID 13035115, compound

Product 1

HCID 13035114HCID 13035114, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

To 6.3 gram NaHCO3 (0.075 mole) dissolved in 75 ml water was added a mixture 50 ml of heptane and 25 ml MeCl2. To the agitated 2-phase system was added 12.2 gram D(-) phenylglycine butyl ester hydrochloride (0.05 mole) over 20 minutes at 12°-14° C. The layers were allowed to settle.

Sources & evidence

ORD record
ord-09c819806b644e8fa262f588778821fb
Source dataset
uspto-grants-1982_03
Patent number
US04322548

Reaction notes

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