Water → HCID 86612199, compound

HRID 2061309Notes

Reaction equation

HRID 2061309 reaction equation
[C:1]1([S:7][CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:9][O:10][S:11](=[O:15])(=[O:14])[O:12]C.O>C(OCC)C>[S:11]([O-:15])([O-:14])(=[O:12])=[O:10].[CH3:8][S+:7]([CH3:9])[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:8][S+:7]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)[CH3:9]

Participants

5

Reactant 3

HCID 962WaterHCID 6497Dimethyl SulfateHCID 7520Thioanisole

Product 1

HCID 86612199HCID 86612199, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

Thioanisol (6.2 g, 0.05 mole) and 6.9 g (0.055 mole) of dimethyl sulfuric acid were stirred at room temperature for 12 hours. Into the reaction solution were added 100 g of water and 50 mL of diethyl ether to separate the water layer to obtain the aqueous solution of the intended dimethylphenyl sulfonium sulfate.

Workup

  1. customto separate the water layer

Sources & evidence

ORD record
ord-8bf62e7c18254e678886eaa5bca99444
Source dataset
uspto-grants-2012_10
Patent number
US08283104B2

Reaction notes

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