m-Chloroperbenzoic acid → 1-Oxo-2-(2-phenylethanesulfinyl)-1lambda~5~-pyridine

HRID 2072264Notes

Reaction equation

HRID 2072264 reaction equation
[C:1]1([CH2:7][CH2:8][S:9][C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][N+:11]=2[O-:16])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C1C=C(Cl)C=C(C(OO)=[O:25])C=1>C(Cl)(Cl)Cl>[C:1]1([CH2:7][CH2:8][S:9]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][N+:11]=2[O-:16])=[O:25])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 139296851-Oxo-2-[(2-phenylethyl)sulfanyl]-1lambda~5~-pyridine

Product 1

HCID 539880001-Oxo-2-(2-phenylethanesulfinyl)-1lambda~5~-pyridine

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

The procedure employed is identical to that of Example 68 using 2.8 gm (0.012 mol) 2-(2-phenylethylthio)pyridine N-oxide in 25 ml of chloroform with 2.4 gm (0.012 mol) MCPBA in 50 ml chloroform.

Sources & evidence

ORD record
ord-4f5388de92684f8a926aaff7b61d143b
Source dataset
uspto-grants-1977_09
Patent number
US04050921

Reaction notes

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