Toluene → Piperitenone

HRID 2072276Notes

Reaction equation

HRID 2072276 reaction equation
[C:1]1([CH3:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[O-2:8].[Ba+2].[CH3:10][C:11](C)([O-])[CH3:12].[K+].[H-].[Na+]>O1CCCC1.C1C=CC=CC=1>[CH3:7][C:1]1[CH2:6][CH2:5][C:4](=[C:11]([CH3:12])[CH3:10])[C:3](=[O:8])[CH:2]=1

Participants

7

Reactant 4

HCID 1140TolueneHCID 24758Sodium hydrideHCID 9855530Barium Oxide Nanoparticle DispersionHCID 23665647Potassium tert-butoxide

Product 1

HCID 381152Piperitenone

Reagents, catalysts & solvents 2

HCID 241BenzeneSolventHCID 8028TetrahydrofuranSolvent2×

Procedure

sodium t-pentoxide, toluene; barium oxide, benzene; potassium t-butoxide, tetrahydrofuran; sodium hydride, tetrahydrofuran.

Sources & evidence

ORD record
ord-8f80093865e64a24af6404c545463adf
Source dataset
uspto-grants-1977_09
Patent number
US04051102

Reaction notes

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