HRID2072280

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6681

1-Amino-2,4-dibromoanthraquinone

C14H7Br2NO2

HCID517044

Potassium acetate

C2H3KO2

HCID3563365

4-Octadecylaniline

C24H43N

PRODUCTS

生成物

结构：CCCCCCCCCCCCCCCCCCc1ccc(Nc2cc(Br)c(N)c3c2C(=O)c2ccccc2C3=O)cc1

HCID21407064

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

催化剂HCID8895

Cupric acetate

C4H6CuO4

溶剂HCID1049

Pyridine

C5H5N

PROCEDURE

实验过程

A reactor was charged with 10 g of 1-amino-2,4-dibromoanthraquinone, 15 g of p-octadecyl-aniline, 20 g of pyridine, 0.2 g of copper acetate and 2.5 g of potassium acetate, and the reaction was effected at an elevated temperature of 115°-120° C. for 24 hours under stirring. A blue solid of 1-amino-2-bromo-4-p-octadecylanilinoanthraquinone was obtained by the reaction of the formula: ##STR9##

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b1f88d83b0ca4c7c80be16451e4aa1f3
来源数据集: uspto-grants-1977_09
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04051052
来源说明: uspto-grants-1977_09

反应 SMILES

[NH2:1][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[C:5](Br)=[CH:4][C:3]=1[Br:19].[CH2:20]([C:38]1[CH:44]=[CH:43][C:41]([NH2:42])=[CH:40][CH:39]=1)[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37].C([O-])(=O)C.[K+]>C([O-])(=O)C.[Cu+2].C([O-])(=O)C.N1C=CC=CC=1>[NH2:1][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[C:5]([NH:42][C:41]2[CH:43]=[CH:44][C:38]([CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37])=[CH:39][CH:40]=2)=[CH:4][C:3]=1[Br:19]