HCID 19860684, compound → HCID 19860670, compound

HRID 2072862Notes

Reaction equation

HRID 2072862 reaction equation
[N+:1]([C:4]1[CH:25]=[CH:24][CH:23]=[CH:22][C:5]=1[O:6][CH2:7][C:8]([CH3:21])([CH3:20])[CH2:9][O:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=1[N+:17]([O-])=O)([O-])=O.[H][H]>CN(C=O)C.[Ni]>[NH2:17][C:12]1[CH:13]=[CH:14][CH:15]=[CH:16][C:11]=1[O:10][CH2:9][C:8]([CH3:21])([CH3:20])[CH2:7][O:6][C:5]1[CH:22]=[CH:23][CH:24]=[CH:25][C:4]=1[NH2:1]

Participants

5

Reactant 2

HCID 19860684HCID 19860684, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 19860670HCID 19860670, compound

Reagents, catalysts & solvents 2

HCID 935NickelCatalystHCID 6228DimethylformamideSolvent

Procedure

343 g 1,3-bis(2-nitrophenoxy)-2,2-dimethylpropane were hydrogenated at 60° C./50 bar in 1800 ml DMF in the presence of 53 g Raney nickel. After the uptake of hydrogen had stopped, the catalyst was filtered off and the solvent was removed in vacuo.

Workup

  1. customwere hydrogenated at 60° C.
  2. filtrationthe catalyst was filtered off
  3. customthe solvent was removed in vacuo

Sources & evidence

ORD record
ord-1b135adb3cd5478897cc294858f8ea8e
Source dataset
uspto-grants-1990_04
Patent number
US04914238

Reaction notes

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