Pyridine → HCID 123606999, compound

HRID 2083179Notes

Reaction equation

HRID 2083179 reaction equation
[C:1]1([CH:7]([SiH2:14][CH2:15][CH2:16][OH:17])[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:18]([O:20][P:21](Cl)(=[O:25])[O:22][CH2:23][CH3:24])[CH3:19].N1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[P:21]([O:17][CH2:16][CH2:15][SiH2:14][CH:7]([C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1)[C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)([O:22][CH2:23][CH3:24])([O:20][CH2:18][CH3:19])=[O:25]

Participants

5

Reactant 3

HCID 1049PyridineHCID 13139Diethyl chlorophosphateHCID 123697742HCID 123697742, compound

Product 1

HCID 123606999HCID 123606999, compound

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

The reaction described in Example 10 was carried out using 2-(diphenylmethylsilyl)-ethanol (2.25 g), diethylphosphorochloridate (1.35 g), and pyridine (0.6 g) in carbon tetrachloride (10 ml). Diethyl 2-(diphenylmethylsilyl)ethyl phosphate was obtained as a colourless oil (1.35 g) (C17H23Si O4P requires: C, 60.5%; H, 7.1%; Found: C 63.4%; H, 7.8%).

Sources & evidence

ORD record
ord-35b8946bef7f4be4a5335c9e5f165e17
Source dataset
uspto-grants-1978_04
Patent number
US04084951

Reaction notes

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