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HRID2098152

反应详情

EQUATION

反应方程式

HRID 2098152 的结构方程式

REACTANTS

反应物

2
结构：CCC[CH2][Sn]([CH2]CCC)([CH2]CCC)[c]1ncco1
HCID15486183

2-(Tributylstannyl)-1,3-oxazole

C15H29NOSn

结构：N#Cc1csc([N+](=O)[O-])c1Br
HCID59168810

未命名化合物

PRODUCTS

生成物

1
结构：N#Cc1csc([N+](=O)[O-])c1-c1ncco1
HCID68754451

未命名化合物

收率 18%

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Cu][I]
催化剂HCID24350

Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

CuI

结构：c1ccc([P](c2ccccc2)(c2ccccc2)[Pd]([P](c2ccccc2)(c2ccccc2)c2ccccc2)([P](c2ccccc2)(c2ccccc2)c2ccccc2)[P](c2ccccc2)(c2ccccc2)c2ccccc2)cc1
催化剂HCID178418397

未命名化合物

PROCEDURE

实验过程

The above titled compound (34 mg, 18%) was synthesized from 4-bromo-5-nitrothiophene-3-carbonitrile (203 mg, 0.87 mmol) and 2-tributylstannyloxazole (0.27 mL, 1.29 mmol), tetrakis(triphenylphosphine)palladium(0) (103 mg, 0.089 mmol) and copper(I) iodide (16 mg, 0.084 mmol) according to methods described herein. LCMS method [4], retention time=1.62 min; MS (ESI) 222.0 (MH+).