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HRID2099342

反应详情

EQUATION

反应方程式

HRID 2099342 的结构方程式

REACTANTS

反应物

3
结构：[Na]
HCID5360545

Sodium

Na

结构：COC(=O)C(O)(c1ccc(F)cc1)c1ccc(F)cc1
HCID12068840

未命名化合物

结构：CN1[C@@H]2CC=C[C@@]1(O)CC2
HCID53629842

未命名化合物

PRODUCTS

生成物

1
结构：CN1[C@@H]2CC=C[C@@]1(OC(=O)C(O)(c1ccc(F)cc1)c1ccc(F)cc1)CC2
HCID86585677

未命名化合物

PROCEDURE

实验过程

11.13 g (0.04 mol) of methyl 4,4′-difluorobenzilate 3d and 5.57 g (0.04 mol) of tropenol are reacted with 0.09 g sodium analogously to Example 3, step 3.2. The product is recrystallized from acetonitrile. Yield: 10.43 g (62% of theory); melting point: 233-235° C.

WORKUP

后处理

  1. customThe product is recrystallized from acetonitrile