Triphenylphosphine → Ethyl 2-vinyloxazole-5-carboxylate

HRID 210013Notes

Reaction equation

HRID 210013 reaction equation
[CH2:1]([CH2:2][CH2:14][CH3:15])[Sn:3]([CH2:4][CH2:5][CH2:6][CH3:7])([CH2:8][CH2:9][CH2:10][CH3:11])[CH:12]=[CH2:13].[Cl:16][c:17]1[o:18][c:19]([C:22](=[O:23])[O:24][CH2:25][CH3:26])[cH:20][n:21]1.[O:27]1[CH2:28][CH2:29][O:30][CH2:31][CH2:32]1.[Pd:33]([Cl:34])[Cl:35].[c:36]1([P:37]([c:38]2[cH:39][cH:40][cH:41][cH:42][cH:43]2)[c:44]2[cH:45][cH:46][cH:47][cH:48][cH:49]2)[cH:50][cH:51][cH:52][cH:53][cH:54]1.[c:55]1([P:56]([c:57]2[cH:58][cH:59][cH:60][cH:61][cH:62]2)[c:63]2[cH:64][cH:65][cH:66][cH:67][cH:68]2)[cH:69][cH:70][cH:71][cH:72][cH:73]1>>[CH:1](=[CH2:2])[c:17]1[o:18][c:19]([C:22](=[O:23])[O:24][CH2:25][CH3:26])[cH:20][n:21]1

Participants

6

Reactant 5

HCID 11776Triphenylphosphine2×HCID 24290Palladium ChlorideHCID 312751,4-DioxaneHCID 81998TributylvinyltinHCID 26369855Ethyl 2-chloro-1,3-oxazole-5-carboxylate

Product 1

HCID 59607716Ethyl 2-vinyloxazole-5-carboxylate

Sources & evidence

ORD record
ord-fad4fafe6b424fb2a0330e504d65998a
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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