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HRID2100693

反应详情

EQUATION

反应方程式

HRID 2100693 的结构方程式

REACTANTS

反应物

4
结构：[H-].[Na+]
HCID24758

Sodium hydride

HNa

结构：CS(=O)(=O)Cl
HCID31297

Methanesulfonyl chloride

CH3ClO2S

结构：CN1C(=O)NC(=O)C1(C)C
HCID81295

1,5,5-Trimethylimidazolidine-2,4-dione

C6H10N2O2

结构：C=C(c1ccc(CO)cc1)c1cc2c(cc1C)C(C)(C)CCC2(C)C
HCID57799975

未命名化合物

PRODUCTS

生成物

1
结构：C=C(c1ccc(CN2C(=O)N(C)C(C)(C)C2=O)cc1)c1cc2c(cc1C)C(C)(C)CCC2(C)C
HCID11408499

未命名化合物

收率 38.2%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCN(CC)CC
溶剂HCID8471

Triethylamine

C6H15N

PROCEDURE

实验过程

Adopting the procedure outlined for example 9 using 40.0 mg (0.12 mmol) of {4-[1-(3,5,5,8,8-Pentamethyl-5,6,7,8-tetrahydro-naphthalen-2-yl)-vinyl]-phenyl}-methanol, 0.05 mL of Methanesulfonyl chloride, 0.10 mL of NEt3, 300 mg of 1,5,5-trimethyl-hydantoin, and 51 mg of NaH, 21.0 mg of the product was obtained.