Diethylamine → HCID 178464165, compound

HRID 2116850Notes

Reaction equation

HRID 2116850 reaction equation
[CH2:1]([NH:3][CH2:4][CH3:5])[CH3:2].[Cl:6]([O-:10])(=[O:9])(=[O:8])=[O:7].[CH3:11][N:12]([C+:14]([N:16]([CH3:18])[CH3:17])Cl)[CH3:13]>O>[Cl:6]([O-:10])(=[O:9])(=[O:8])=[O:7].[CH3:11][N:12]([CH3:13])[C:14]([N:16]([CH3:18])[CH3:17])=[N+:3]([CH2:4][CH3:5])[CH2:1][CH3:2]

Participants

4

Reactant 2

HCID 8021DiethylamineHCID 178483693HCID 178483693, compound

Product 1

HCID 178464165HCID 178464165, compoundYield 89.6%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

3.42 g (46.8 mmol) of diethylamine are added with stirring and ice-cooling to 5.00 g (21.3 mmol) of bis(dimethylamino)chlorocarbenium perchlorate. The reaction mixture is subsequently stirred for 1 hour at room temperature and subsequently added to 20 ml of water. The organic phase is separated off and washed with 20 ml of water. The liquid is subsequently dried at 50° C. under reduced pressure (7.0 Pa), giving 5.17 g of N,N,N′,N′-tetramethyl-N″,N″-diethylguanidinium perchlorate, corresponding to a yield of 89.6%.

Workup

  1. stirringThe reaction mixture is subsequently stirred for 1 hour at room temperature
  2. customThe organic phase is separated off
  3. washwashed with 20 ml of water
  4. customThe liquid is subsequently dried at 50° C. under reduced pressure (7.0 Pa)

Sources & evidence

ORD record
ord-ce97741ab6fe416e93176c4cc09e4b18
Source dataset
uspto-grants-2008_10
Patent number
US07439395B2

Reaction notes

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