2,6-Dimethylaniline → HCID 59816215, compound

HRID 2118149Notes

Reaction equation

HRID 2118149 reaction equation
[CH3:1][C:2]1[CH:8]=[CH:7][CH:6]=[C:5]([CH3:9])[C:3]=1[NH2:4].[CH2:10]1[C:23]2[C:14](=[N:15][C:16]3[C:17](=O)[CH2:18][CH2:19][CH2:20][C:21]=3[CH:22]=2)[C:13](=O)[CH2:12][CH2:11]1>>[CH3:1][C:2]1[CH:8]=[CH:7][CH:6]=[C:5]([CH3:9])[C:3]=1[N:4]=[C:13]1[C:14]2[C:23](=[CH:22][C:21]3[CH2:20][CH2:19][CH2:18][C:17](=[N:4][C:3]4[C:5]([CH3:9])=[CH:6][CH:7]=[CH:8][C:2]=4[CH3:1])[C:16]=3[N:15]=2)[CH2:10][CH2:11][CH2:12]1

Participants

3

Reactant 2

HCID 68962,6-DimethylanilineHCID 355603HCID 355603, compound

Product 1

HCID 59816215HCID 59816215, compound

Procedure

was synthesized by methods similar to those in Examples 3 and 4: 2,6-dimethylaniline was condensed with 2,3,7,8-tetrahydro-1H,6H-acridine-4,5-dione to yield 4,5-bis[2,6-dimethylphenylimino]-1,2,3,4,5,6,7,8-octahydroacridine (3). The complexation of (3) with FeCl2.4H2O was carried out with azeotropic removal of methanol in benzene. The structure of final complex was proved by X-ray analysis.

Workup

  1. customwas synthesized by methods similar to those in Examples 3 and 4

Sources & evidence

ORD record
ord-f559d1690d8c4a059cfb28dede4d0b29
Source dataset
uspto-grants-2008_10
Patent number
US07442819B2

Reaction notes

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