Calcium Carbonate → HCID 15072431, compound

HRID 2118811Notes

Reaction equation

HRID 2118811 reaction equation
Cl[C:2]1[CH:16]=[CH:15][C:14]([N+:17]([O-:19])=[O:18])=[CH:13][C:3]=1[C:4]([C:6]1[CH:11]=[CH:10][C:9]([CH3:12])=[CH:8][CH:7]=1)=[O:5].[CH3:20][CH:21]1[CH2:26][CH2:25][NH:24][CH2:23][CH2:22]1.C(=O)([O-])[O-].[Ca+2]>C(O)C>[CH3:20][CH:21]1[CH2:26][CH2:25][N:24]([C:2]2[CH:16]=[CH:15][C:14]([N+:17]([O-:19])=[O:18])=[CH:13][C:3]=2[C:4]([C:6]2[CH:11]=[CH:10][C:9]([CH3:12])=[CH:8][CH:7]=2)=[O:5])[CH2:23][CH2:22]1

Participants

5

Reactant 3

HCID 10112Calcium CarbonateHCID 693814-MethylpiperidineHCID 884746HCID 884746, compound

Product 1

HCID 15072431HCID 15072431, compoundYield 95%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

Proceeding as in example 2, with 0.045 mole (13 g) of 2-chloro-4'-methyl-5-nitro-benzophenone, 0.1 mole (11.3 cm3) of 4-methyl piperidine and 0.045 mole (6.2 g) of calcium carbonate mixed in ethanol, 14 g (Yield: 95%) of the expected product are obtained. M.P. 86° C.

Sources & evidence

ORD record
ord-4fa9e9a6862f4bbf8d2d4efa13768816
Source dataset
uspto-grants-1987_07
Patent number
US04680402

Reaction notes

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