Calcium Carbonate → HCID 15072434, compound

HRID 2118814Notes

Reaction equation

HRID 2118814 reaction equation
Cl[C:2]1[CH:17]=[CH:16][C:15]([N+:18]([O-:20])=[O:19])=[CH:14][C:3]=1[C:4]([C:6]1[CH:11]=[CH:10][C:9]([O:12][CH3:13])=[CH:8][CH:7]=1)=[O:5].C(=O)([O-])[O-].[Ca+2].[CH3:26][CH:27]1[CH2:32][CH2:31][NH:30][CH2:29][CH2:28]1>C(O)C>[CH3:26][CH:27]1[CH2:32][CH2:31][N:30]([C:2]2[CH:17]=[CH:16][C:15]([N+:18]([O-:20])=[O:19])=[CH:14][C:3]=2[C:4]([C:6]2[CH:11]=[CH:10][C:9]([O:12][CH3:13])=[CH:8][CH:7]=2)=[O:5])[CH2:29][CH2:28]1

Participants

5

Reactant 3

HCID 10112Calcium CarbonateHCID 693814-MethylpiperidineHCID 885157(2-Chloro-5-nitrophenyl)(4-methoxyphenyl)methanone

Product 1

HCID 15072434HCID 15072434, compoundYield 54.2%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

Proceeding as indicated in example 2, with 0.0635 mole (18.5 g) of 2-chloro-4'-methoxy-5-nitro-benzophenone, 0.076 mole (10.5 g) of calcium carbonate and 0.127 mole (12.57 g) of 4-methyl piperidine in 50 cm3 of ethanol, 12.2 g (Yield: 53%) of the expected product are obtained. M.P. 119° C.

Sources & evidence

ORD record
ord-5d65e4fba00d464db268db625dbd84c8
Source dataset
uspto-grants-1987_07
Patent number
US04680402

Reaction notes

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