Chloride → 2-[2-(2-Bromocyclohexen-1-yl)ethenyl]-1,3,3-trimethylcyclohexene

HRID 2127407Notes

Reaction equation

HRID 2127407 reaction equation
[Br:36][C:37]1=[C:38]([CH:43]=[O:44])[CH2:39][CH2:40][CH2:41][CH2:42]1.[CH2:31]([Li:32])[CH2:33][CH2:34][CH3:35].[CH3:2][C:3]1=[C:4]([CH2:11][P+:12]([c:13]2[cH:14][cH:15][cH:16][cH:17][cH:18]2)([c:19]2[cH:20][cH:21][cH:22][cH:23][cH:24]2)[c:25]2[cH:26][cH:27][cH:28][cH:29][cH:30]2)[C:5]([CH3:9])([CH3:10])[CH2:6][CH2:7][CH2:8]1.[CH3:45][CH2:46][CH2:47][CH2:48][CH2:49][CH3:50].[Cl-:1].[O:51]1[CH2:52][CH2:53][CH2:54][CH2:55]1>>[CH3:2][C:3]1=[C:4]([CH:11]=[CH:43][C:38]2=[C:37]([Br:36])[CH2:42][CH2:41][CH2:40][CH2:39]2)[C:5]([CH3:9])([CH3:10])[CH2:6][CH2:7][CH2:8]1

Participants

7

Reactant 6

HCID 312ChlorideHCID 8028TetrahydrofuranHCID 8058HexaneHCID 10950921Triphenyl((2,6,6-trimethylcyclohex-1-en-1-yl)methyl)phosphoniumHCID 112639462-Bromocyclohexene-1-carbaldehydeHCID 178418339Butyllithium

Product 1

HCID 541212702-[2-(2-Bromocyclohexen-1-yl)ethenyl]-1,3,3-trimethylcyclohexene

Sources & evidence

ORD record
ord-1c4a6dfdc1a34ea7b605a8494d3e60cc
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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