Acetate → HCID 178467303, compound

HRID 2133523Notes

Reaction equation

HRID 2133523 reaction equation
[C:86]([O-:87])(=[O:88])[CH3:89].[C:91]([O-:92])(=[O:93])[CH3:94].[CH3:83][C:84]#[N:85].[CH3:95][CH2:96][O:97][C:98](=[O:99])[CH3:100].[CH:46]([N:47]([CH:48]([CH3:49])[CH3:50])[CH2:51][CH3:52])([CH3:53])[CH3:54].[Cl:79][CH:80]([Cl:81])[CH3:82].[F:55][CH2:56][CH2:57][O:58][CH2:59][CH:60]1[N:61]([C:66](=[O:67])[O:68][CH2:69][c:70]2[cH:71][cH:72][c:73]([N+:76](=[O:77])[O-:78])[cH:74][cH:75]2)[CH2:62][CH:63]([SH:65])[CH2:64]1.[N+:1](=[C:3]([C:4](=[O:5])[O:6][CH2:7][c:8]1[cH:9][cH:10][c:11]([N+:14](=[O:15])[O-:16])[cH:12][cH:13]1)[C:17](=[O:2])[CH:18]([CH3:19])[CH:20]1[NH:21][C:22](=[O:27])[CH:23]1[CH:24]([CH3:25])[OH:26])=[N-:28].[OH2:101].[P:29]([Cl:30])([O:31][c:32]1[cH:33][cH:34][cH:35][cH:36][cH:37]1)([O:38][c:39]1[cH:40][cH:41][cH:42][cH:43][cH:44]1)=[O:45].[Rh+2:90]>>[C:3]1([C:4](=[O:5])[O:6][CH2:7][c:8]2[cH:9][cH:10][c:11]([N+:14](=[O:15])[O-:16])[cH:12][cH:13]2)=[C:17]([S:65][CH:63]2[CH2:62][N:61]([C:66](=[O:67])[O:68][CH2:69][c:70]3[cH:71][cH:72][c:73]([N+:76](=[O:77])[O-:78])[cH:74][cH:75]3)[CH:60]([CH2:59][O:58][CH2:57][CH2:56][F:55])[CH2:64]2)[CH:18]([CH3:19])[CH:20]2[N:21]1[C:22](=[O:27])[CH:23]2[CH:24]([CH3:25])[OH:26]

Participants

11

Reactant 10

HCID 175Acetate2×HCID 962WaterHCID 6342AcetonitrileHCID 63651,1-DichloroethaneHCID 8857Ethyl AcetateHCID 75654Diphenyl chlorophosphateHCID 81531DiisopropylethylamineHCID 185497Rhodium, ion(Rh2)HCID 76069594(R)-4-Nitrobenzyl 2-diazo-4-((2R,3S)-3-((R)-1-hydroxy-ethyl)-4-oxoazetidin-2-yl)-3-oxopentanoateHCID 178525202HCID 178525202, compound

Product 1

HCID 178467303HCID 178467303, compound

Sources & evidence

ORD record
ord-41c0258a4233482bb32d422cf00777ee
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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