HRID2135179

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID8028

Tetrahydrofuran

C4H8O

HCID28486

Lithium ion

Li+

HCID3280088

未命名化合物

HCID13374594

3-(Benzyloxy)pyridine-2-carbaldehyde

C13H11NO2

结构：O=C(O)c1ccc(CC[P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

HCID18974097

未命名化合物

PRODUCTS

生成物

结构：O=C(O)c1ccc(CC=Cc2ncccc2OCc2ccccc2)cc1

HCID54449459

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b08e9f9f51124978b6b72c0ba2dc0b83
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (4/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (4/10)

反应 SMILES

[Br-:1].[C:2](=[O:3])([OH:4])[c:5]1[cH:6][cH:7][c:8]([CH2:11][CH2:12][P+:13]([c:14]2[cH:15][cH:16][cH:17][cH:18][cH:19]2)([c:20]2[cH:21][cH:22][cH:23][cH:24][cH:25]2)[c:26]2[cH:27][cH:28][cH:29][cH:30][cH:31]2)[cH:9][cH:10]1.[CH2:42]([c:43]1[cH:44][cH:45][cH:46][cH:47][cH:48]1)[O:49][c:50]1[c:51]([CH:56]=[O:57])[n:52][cH:53][cH:54][cH:55]1.[CH2:58]1[O:59][CH2:60][CH2:61][CH2:62]1.[CH3:32][Si:33]([N-:34][Si:35]([CH3:36])([CH3:37])[CH3:38])([CH3:39])[CH3:40].[Li+:41]>>[C:2](=[O:3])([OH:4])[c:5]1[cH:6][cH:7][c:8]([CH2:11][CH:12]=[CH:56][c:51]2[c:50]([O:49][CH2:42][c:43]3[cH:44][cH:45][cH:46][cH:47][cH:48]3)[cH:55][cH:54][cH:53][n:52]2)[cH:9][cH:10]1