HRID213598

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8028

Tetrahydrofuran

C4H8O

HCID12679

Hexamethylphosphoramide

C6H18N3OP

HCID13831

Tributylphosphine

C12H27P

HCID15096

Tributyltin chloride

C12H27ClSn

HCID30165

Iodide ion

I-

HCID2757087

1-Bromo-2-octyne

C8H13Br

HCID121493839

未命名化合物

HCID178418339

未命名化合物

PRODUCTS

生成物

结构：CCCCCC#CCC1(O[SiH](C)C)C(=O)CC(C(C)(C)C)C1CCCC

HCID178442715

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-42de92dc75ba48409697338b8205fcbd
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (6/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (6/10)

反应 SMILES

[Br:48][CH2:49][C:50]#[C:51][CH2:52][CH2:53][CH2:54][CH2:55][CH3:56].[C:20]([CH3:21])([CH3:22])([CH3:23])[CH:24]1[CH:25]=[C:26]([O:30][SiH:31]([CH3:32])[CH3:33])[C:27](=[O:29])[CH2:28]1.[CH2:15]([CH2:16][CH2:17][CH3:18])[Li:19].[CH2:2]([P:3]([CH2:4][CH2:5][CH2:6][CH3:7])[CH2:8][CH2:9][CH2:10][CH3:11])[CH2:12][CH2:13][CH3:14].[CH2:34]([Sn:35]([Cl:36])([CH2:37][CH2:38][CH2:39][CH3:40])[CH2:41][CH2:42][CH2:43][CH3:44])[CH2:45][CH2:46][CH3:47].[CH3:62][N:63]([CH3:64])[P:65](=[O:66])([N:67]([CH3:68])[CH3:69])[N:70]([CH3:71])[CH3:72].[I-:1].[O:57]1[CH2:58][CH2:59][CH2:60][CH2:61]1>>[CH2:15]([CH2:16][CH2:17][CH3:18])[CH:25]1[CH:24]([C:20]([CH3:21])([CH3:22])[CH3:23])[CH2:28][C:27](=[O:29])[C:26]1([O:30][SiH:31]([CH3:32])[CH3:33])[CH2:49][C:50]#[C:51][CH2:52][CH2:53][CH2:54][CH2:55][CH3:56]