Dimethylformamide → 4-Benzyloxy-3-hydroxybenzaldehyde

HRID 214483Notes

Reaction equation

HRID 214483 reaction equation
[Br:1][CH2:2][c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1.[C:19](=[O:20])([O-:21])[O-:22].[CH2:26]([N+:27]([CH2:28][CH2:29][CH2:30][CH3:31])([CH2:32][CH2:33][CH2:34][CH3:35])[CH2:36][CH2:37][CH2:38][CH3:39])[CH2:40][CH2:41][CH3:42].[CH3:43][N:44]([CH3:45])[CH:46]=[O:47].[Cs+:23].[Cs+:24].[I-:25].[OH:9][c:10]1[cH:11][c:12]([CH:13]=[O:14])[cH:15][cH:16][c:17]1[OH:18]>>[CH2:2]([c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1)[O:18][c:17]1[c:10]([OH:9])[cH:11][c:12]([CH:13]=[O:14])[cH:15][cH:16]1

Participants

8

Reactant 7

HCID 6228DimethylformamideHCID 7498Benzyl BromideHCID 87683,4-DihydroxybenzaldehydeHCID 16028TetrabutylammoniumHCID 19660Carbonate IonHCID 30165Iodide IonHCID 104967Cesium cation2×

Product 1

HCID 5613694-Benzyloxy-3-hydroxybenzaldehyde

Sources & evidence

ORD record
ord-8a44352463444c2d8e160c53a064ae0c
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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