Potassium Cation → 4-(Benzyloxy)-3-bromobenzaldehyde

HRID 2152526Notes

Reaction equation

HRID 2152526 reaction equation
[Br:1][CH2:2][c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1.[Br:9][c:10]1[cH:11][c:12]([CH:13]=[O:14])[cH:15][cH:16][c:17]1[OH:18].[C:19](=[O:20])([O-:21])[O-:22].[CH2:26]([N+:27]([CH2:28][CH2:29][CH2:30][CH3:31])([CH2:32][CH2:33][CH2:34][CH3:35])[CH2:36][CH2:37][CH2:38][CH3:39])[CH2:40][CH2:41][CH3:42].[CH3:43][N:44]([CH3:45])[CH:46]=[O:47].[I-:25].[K+:23].[K+:24]>>[CH2:2]([c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1)[O:18][c:17]1[c:10]([Br:9])[cH:11][c:12]([CH:13]=[O:14])[cH:15][cH:16]1

Participants

8

Reactant 7

HCID 813Potassium Cation2×HCID 6228DimethylformamideHCID 7498Benzyl BromideHCID 16028TetrabutylammoniumHCID 19660Carbonate IonHCID 30165Iodide IonHCID 763083-Bromo-4-hydroxybenzaldehyde

Product 1

HCID 14943384-(Benzyloxy)-3-bromobenzaldehyde

Sources & evidence

ORD record
ord-b20f7dc86e174b3988594275c00a1c0e
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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