1-Pentanol → Pentyl anthranilate

HRID 2163566Notes

Reaction equation

HRID 2163566 reaction equation
[CH3:1][O:2][C:3](=[O:11])[C:4]1[C:5](=[CH:7][CH:8]=[CH:9][CH:10]=1)[NH2:6].[CH2:12](O)[CH2:13][CH2:14][CH2:15]C.C(=O)([O-])[O-].[K+].[K+]>>[CH2:1]([O:2][C:3](=[O:11])[C:4]1[C:5](=[CH:7][CH:8]=[CH:9][CH:10]=1)[NH2:6])[CH2:12][CH2:13][CH2:14][CH3:15]

Participants

4

Reactant 3

HCID 62761-PentanolHCID 8635Methyl AnthranilateHCID 11430Potassium Carbonate

Product 1

HCID 100495Pentyl anthranilateYield 95%

Procedure

450 parts of anthranilic acid methyl ester, 500 parts of n-pentanol and 10 parts of potassium carbonate are reacted as described in Example 1. The reaction lasts for about 8 hours. There are obtained 588 parts of anthranilic acid n-pentyl ester (boiling point 132°-135° C. under 0.3-0.4 mm Hg; nD25 1.538; purity according to gas chromatography 99%, below 0.2% of anthranilic acid methyl ester). Yield: 95% of the theory.

Sources & evidence

ORD record
ord-a15259988ba44ed3914d06ff6705c0d0
Source dataset
uspto-grants-1979_01
Patent number
US04135050

Reaction notes

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