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HRID2172968

反应详情

EQUATION

反应方程式

HRID 2172968 的结构方程式

REACTANTS

反应物

3
结构：CS(=O)[O-].[Na+]
HCID2733271

Sodium methanesulphinate

CH3NaO2S

结构：COC(=O)CCS(=O)[O-].[Na+]
HCID23665669

Sodium 3-methoxy-3-oxopropane-1-sulfinate

C4H7NaO4S

结构：CC(C)(C)OC(=O)NC1(c2ccc(I)o2)CC1
HCID67115732

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)OC(=O)NC1(c2ccc(S(C)(=O)=O)o2)CC1
HCID68377483

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：[Cu][I]
催化剂HCID24350

Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

CuI

PROCEDURE

实验过程

[1-(5-Methanesulfonyl-furan-2-yl)-cyclopropyl]-carbamic acid tert-butyl ester is prepared from [1-(5-iodo-furan-2-yl)-cyclopropyl]-carbamic acid tert-butyl ester (0.500 g, 1.43 mmol) according to the copper (I) iodide-mediated coupling procedure described in Example 19; however, sodium methanesulfinate is used as coupling partner instead of sodium 3-methoxy-3-oxopropane-1-sulfinate.