Cyclohexanone → HCID 68433282, compound

HRID 2192800Notes

Reaction equation

HRID 2192800 reaction equation
[C:1]1(=[O:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[CH:8](OCC)=[O:9].[O-]CC.[Na+:16]>C(OCC)C>[O:7]=[C:1]1[CH2:6][CH2:5][CH2:4][CH2:3][C:2]1=[CH:8][O-:9].[Na+:16]

Participants

5

Reactant 3

HCID 7967CyclohexanoneHCID 8025Ethyl formateHCID 2723922Sodium ethoxide

Product 1

HCID 68433282HCID 68433282, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

Cyclohexanone (30 ml) and ethyl formate (24 ml) were dissolved in diethyl ether (150 ml), sodium ethoxide (21 g) was added under ice-cooling, and the reaction mixture was stirred at room temperature for 10 hr. Insoluble material was collected by filtration, and washed with diethyl ether to give the object compound (49.2 g) as a solid.

Workup

  1. temperaturecooling
  2. filtrationInsoluble material was collected by filtration
  3. washwashed with diethyl ether

Sources & evidence

ORD record
ord-7415159a107841f599f407a99ae1d24d
Source dataset
uspto-grants-2012_12
Patent number
US08329691B2

Reaction notes

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