3,7-Dimethyl-1-octanol → HCID 87841056, compound

HRID 2204671Notes

Reaction equation

HRID 2204671 reaction equation
[CH3:1][CH:2]([CH2:6][CH2:7][CH2:8][CH:9]([CH3:11])[CH3:10])[CH2:3][CH2:4][OH:5].Br[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22].[OH-].[Na+]>[Br-].C([N+](CCCC)(CCCC)CCCC)CCC>[CH3:1][CH:2]([CH2:6][CH2:7][CH2:8][CH:9]([CH3:11])[CH3:10])[CH2:3][CH2:4][O:5][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]

Participants

5

Reactant 3

HCID 77923,7-Dimethyl-1-octanolHCID 81731-BromodecaneHCID 14798Sodium Hydroxide

Product 1

HCID 87841056HCID 87841056, compound

Reagents, catalysts & solvents 1

HCID 74236Tetrabutylammonium BromideCatalyst

Conditions

Temperature
70 °C

Procedure

To 2-L glass flask, 158 g of 3,7-dimethyl-1-octanol, 221 g of 1-bromodecane, 32 g of tetrabutylammonium bromide, and 454 g of aqueous sodium hydroxide (236 g of sodium hydroxide dissolved in 218 g of water) were added, and the mixture was allowed to react under stirring at 70° C. for 5 hours.

Workup

  1. customto react

Sources & evidence

ORD record
ord-50dab05876f040888003755abfcba650
Source dataset
uspto-grants-2016_06
Patent number
US09365789B2

Reaction notes

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