Isobutyraldehyde → HCID 78098441, compound

HRID 2205246Notes

Reaction equation

HRID 2205246 reaction equation
[CH2:1]=[C:2]([C:4]1(C=O)[CH2:9][CH2:8][CH:7]=[CH:6][CH2:5]1)[CH3:3].[CH:12](=[O:16])[CH:13]([CH3:15])[CH3:14].B(F)(F)F.C[CH2:22][O:23]CC>ClCCCl>[CH:22]([O:16][CH:12]([CH2:3][C:2](=[C:4]1[CH2:9][CH2:8][CH:7]=[CH:6][CH2:5]1)[CH3:1])[CH:13]([CH3:15])[CH3:14])=[O:23]

Participants

5

Reactant 3

HCID 6561IsobutyraldehydeHCID 8000Boron trifluoride etherateHCID 87467929HCID 87467929, compound

Product 1

HCID 78098441HCID 78098441, compoundYield 697.2%

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent

Procedure

Following the general procedure as described in Example 1, 1-(prop-1-en-2-yl)cyclohex-3-enecarbaldehyde (1.50 g, 10 mmol), isobutyraldehyde (0.86 g, 12 mmol) and boron trifluoride etherate (0.14 g, 1.0 mmol) in 1,2-dichloroethane (10 mL) were reacted to give the title product as a colorless liquid (1.55 g, 70% yield). Mixture of E/Z isomers in a ratio 2:1.

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-6aba24a65c494bf49423e20bbe10efda
Source dataset
uspto-grants-2016_06
Patent number
US09371262B2

Reaction notes

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