Acetaldehyde → HCID 78098442, compound

HRID 2205247Notes

Reaction equation

HRID 2205247 reaction equation
[CH:1]([C:3]1(C=O)[CH2:8][CH2:7][CH:6]=[CH:5][CH2:4]1)=[CH2:2].[CH:11](=[O:13])[CH3:12].B(F)(F)F.C[CH2:19][O:20]CC>ClCCCl>[CH:19]([O:13][CH:11]([CH2:2][CH:1]=[C:3]1[CH2:8][CH2:7][CH:6]=[CH:5][CH2:4]1)[CH3:12])=[O:20]

Participants

5

Reactant 3

HCID 177AcetaldehydeHCID 8000Boron trifluoride etherateHCID 895255261-Ethenyl-3-cyclohexene-1-carboxaldehyde

Product 1

HCID 78098442HCID 78098442, compoundYield 399.5%

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent

Procedure

Following the general procedure as described in Example 1, 1-vinylcyclohex-3-enecarbaldehyde (1.50 g, 10 mmol), acetaldehyde (0.53 g, 12 mmol) and boron trifluoride etherate (0.14 g, 1.0 mmol) in 1,2-dichloroethane (10 mL) were reacted to give the title product as a colorless liquid (0.72 g, 40% yield). Mixture of E/Z isomers in a ratio 1:1.

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-03828a84941e4483a3119fd715b88554
Source dataset
uspto-grants-2016_06
Patent number
US09371262B2

Reaction notes

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