Acetaldehyde → HCID 89525575, compound

HRID 2205251Notes

Reaction equation

HRID 2205251 reaction equation
C[C:2]1[CH:3]([C:11](=O)C)[CH2:4][CH:5]2[CH:7]([CH:8]=1)[C:6]2([CH3:10])[CH3:9].[CH:14](=[O:16])[CH3:15].B(F)(F)F.[CH3:21][CH2:22][O:23]CC>ClCCCl>[C:14]([O:23][C@H:22]([C@@H:4]1[C:3]([CH3:11])=[CH:2][CH2:8][C@@H:7]2[C@H:5]1[C:6]2([CH3:9])[CH3:10])[CH3:21])(=[O:16])[CH3:15]

Participants

5

Reactant 3

HCID 177AcetaldehydeHCID 8000Boron trifluoride etherateHCID 44079Ethanone, 1-(4,7,7-trimethylbicyclo[4.1.0]hept-4-en-3-yl)-

Product 1

HCID 89525575HCID 89525575, compoundYield 818.6%

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent

Procedure

Following the general procedure as described in Example 1, 1-(4,7,7-trimethylbicyclo[4.1.0]hept-4-en-3-yl)ethanone (1.78 g, 10 mmol), acetaldehyde (0.53 g, 12 mmol) and boron trifluoride etherate (0.14 g, 1.0 mmol) in 1,2-dichloroethane (10 mL) were reacted to give the title product as a colorless liquid (1.82 g, 82% yield).

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-387d9fbbe9ec448e910210f045ce9721
Source dataset
uspto-grants-2016_06
Patent number
US09371262B2

Reaction notes

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