Tin tetrachloride → HCID 131735809, compound

HRID 2205264Notes

Reaction equation

HRID 2205264 reaction equation
[CH3:1][C:2]1([C:10]([CH3:12])=[CH2:11])[CH2:7][CH2:6][CH:5]([CH3:8])[CH2:4][C:3]1=[O:9].[CH:13](=[N:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH2:14][CH2:15][CH3:16].Cl[Sn](Cl)(Cl)Cl>ClCCCl>[CH2:13]([N:17]1[CH:18]([CH2:19][CH2:20][CH3:21])[CH2:12][C:10]([CH3:11])=[C:2]([CH3:1])[CH2:7][CH2:6][C@H:5]([CH3:8])[CH2:4][C:3]1=[O:9])[CH2:14][CH2:15][CH3:16]

Participants

5

Reactant 3

HCID 24287Tin tetrachlorideHCID 94840N-ButylidenebutylamineHCID 579671HCID 579671, compound

Product 1

HCID 131735809HCID 131735809, compoundYield 76%

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent

Procedure

Following the general procedure as described in Example 17, 2,5-dimethyl-2-(prop-1-en-2-yl)cyclohexanone (1.06 g, 6.38 mmol), N-butylidenebutan-1-amine (0.97 g, 7.65 mmol), and SnCl4 (1.66 g, 6.38 mmol) in 1,2-dichloroethane (65 ml) were reacted to give the title product as a colorless liquid (1.28 g, 76% yield). 3 isomers in a ratio of 1:2:8.

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-d9c1fa03c0c248c8a0fd9b953e8459de
Source dataset
uspto-grants-2016_06
Patent number
US09371262B2

Reaction notes

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