1,2-Dichloroethane → HCID 118511020, compound

HRID 2206360Notes

Reaction equation

HRID 2206360 reaction equation
[CH3:1][O:2][C:3]1[C:16]2[C:17]3=[C:18]4[C:13](=[CH:14][CH:15]=2)[CH:12]=[CH:11][CH:10]=[C:9]4[CH:8]=[CH:7][C:6]3=[CH:5][CH:4]=1.[CH:19]1[C:28]2[C:23](=[CH:24][CH:25]=[CH:26][CH:27]=2)[CH:22]=[CH:21][C:20]=1[C:29](Cl)=[O:30].ClCCCl.[Cl-].[Al+3].[Cl-].[Cl-]>CO>[CH:19]1[C:28]2[C:23](=[CH:24][CH:25]=[CH:26][CH:27]=2)[CH:22]=[CH:21][C:20]=1[C:29]([C:4]1[CH:5]=[C:6]2[C:17]3=[C:18]4[C:13]([CH:12]=[CH:11][CH:10]=[C:9]4[CH:8]=[CH:7]2)=[CH:14][CH:15]=[C:16]3[C:3]=1[O:2][CH3:1])=[O:30]

Participants

6

Reactant 4

HCID 111,2-DichloroethaneHCID 752462-Naphthoyl chlorideHCID 1602361-MethoxypyreneHCID 6451240Aluminum(III) Chloride

Product 1

HCID 118511020HCID 118511020, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Methoxy pyrene (23.20 g, 0.1 mol), 2-naphthoyl chloride (56.8 g, 0.333 mol), and 1,2-dichloroethane (325 g) were put in a flask. Then, aluminum chloride (29.4 g, 0.12 mol) was slowly added to the solution at ambient temperature, and the mixture was agitated for 2 hours. When the reaction was terminated, a precipitate obtained by adding methanol thereto was filtered, obtaining 2-naphthoyl methoxy pyrene.

Workup

  1. customWhen the reaction was terminated
  2. customa precipitate obtained
  3. filtrationthereto was filtered

Sources & evidence

ORD record
ord-91f01e50c4e5470eb1753a1659ee35c0
Source dataset
uspto-grants-2016_06
Patent number
US09371444B2

Reaction notes

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