1-Butene → 1-Nonene

HRID 2211190Notes

Reaction equation

C=CCC.C=CCCCCCC.[CH2:13](O)[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21]>>[CH2:13]=[CH:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21]

Participants

Reactant 3

HCID 78441-Butene

HCID 81251-Octene

HCID 89141-Nonanol2×

Product 1

HCID 312851-Nonene

Procedure

Another way to obtain didecyl phthalic mixtures is described in European Patent Application 04 24 767. The esters are prepared by a multi-stage process by dimerization of butene mixtures, hydroformylation, and hydrogenation of the resulting octene mixture to a nonanol mixture, dehydration of the nonanol mixture to form a nonene mixture, followed by hydroformylation and hydrogenation of the nonene mixture to form a decanol mixture.

Workup

customAnother way to obtain didecyl phthalic mixtures

Sources & evidence

ORD record: ord-f2ce619b568b45b38aad2db4bd6c7eab
Source dataset: uspto-grants-1995_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05462986

Reaction notes

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