Pivalic acid → 3-(Benzyloxy)-2,2-dimethylpropanoic acid

HRID 2211579Notes

Reaction equation

HRID 2211579 reaction equation
[C:1]([O:20][CH3:21])(=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7]C/C=C\CCCCCCCC.[C:22]([OH:28])(=[O:27])[C:23](C)([CH3:25])[CH3:24]>>[CH2:1]([O:20][CH2:21][C:23]([CH3:25])([CH3:24])[C:22]([OH:28])=[O:27])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

3

Reactant 2

HCID 6417Pivalic acidHCID 5364509Methyl Oleate2×

Product 1

HCID 134782883-(Benzyloxy)-2,2-dimethylpropanoic acid

Procedure

The spectroscopic data of the compound have already been reported further back in the text. Nafion SAC 13 was used as catalyst for acyloxylating methyl oleate. The following reaction conditions were selected: catalyst velocity 4 mmol/g of catalyst, molar excess of pivalic acid compared to methyl oleate=25, temperature 120° C., batch reaction under atmospheric pressure, reaction time 24 h.

Workup

  1. customThe following reaction conditions

Sources & evidence

ORD record
ord-f74b4594fba64171bc1542a310193146
Source dataset
uspto-grants-2006_09
Patent number
US07101831B2

Reaction notes

Loading…