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HRID2215244

反应详情

EQUATION

反应方程式

HRID 2215244 的结构方程式

REACTANTS

反应物

2
结构：CC[SiH](CC)CC
HCID12052

Silane, triethyl-

C6H16Si

结构：CCO[C@H](C(=O)OC)[C@H](O)c1c(C)cc(OCc2ccccc2)cc1C
HCID68615974

未命名化合物

PRODUCTS

生成物

1
结构：CCO[C@@H](Cc1c(C)cc(OCc2ccccc2)cc1C)C(=O)OC
HCID68616291

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：O=C(O)C(F)(F)F
溶剂HCID6422

未命名化合物

PROCEDURE

实验过程

In analogy to the procedure described in example 48 f], (2S,3R)-3-(4-benzyloxy-2,6-dimethyl-phenyl)-2-ethoxy-3-hydroxy-propionic acid methyl ester was treated with triethylsilane in trifluoroacetic acid to yield (2S)-3-(4-benzyloxy-2,6-dimethyl-phenyl)-2-ethoxy-propionic acid methyl ester as colorless liquid.