m-Chloroperbenzoic acid → HCID 12518282, compound

HRID 2226472Notes

Reaction equation

HRID 2226472 reaction equation
C(S[CH2:9][CH2:10][Cl:11])CCCCCC.Cl[C:13]1[CH:18]=[CH:17][CH:16]=[C:15]([C:19](OO)=O)[CH:14]=1.[S:23](S([O-])=O)([O-:26])(=O)=[O:24].[Na+].[Na+].C(=O)([O-])O.[Na+]>C(Cl)Cl>[CH2:14]([S:23]([CH2:9][CH2:10][Cl:11])(=[O:26])=[O:24])[CH2:13][CH2:18][CH2:17][CH2:16][CH2:15][CH3:19]

Participants

6

Reactant 4

HCID 70297m-Chloroperbenzoic acid2×HCID 304371NSC196182HCID 516892Sodium BicarbonateHCID 656671Sodium Pyrosulfite

Product 1

HCID 12518282HCID 12518282, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Dissolve 2-chloroethyl heptyl sulfide (1.0 g, 5.13 mmol) in methylene chloride (50 mL). Add metachloroperbenzoic acid (3.2 g, 15 mmol) portionwise and stir at room temperature for 1 hour. Add addition metachloroperbenzoic acid (1.0 g) and stir at room temperature for 2 hours. Treat with saturated sodium meta bisulfite (until negative starch-iodide test) and basify with saturated sodium hydrogen carbonate. Extract with methylene chloride (2×25 mL), dry (MgSO4) and evaporate in vacuo to yield 1.23 g 2-chloroethyl heptyl sulfone as a white solid; MS (CI/CH4) m/z 227(M+1).

Workup

  1. additionAdd
  2. extractionExtract with methylene chloride (2×25 mL)
  3. dry with materialdry (MgSO4)
  4. customevaporate in vacuo

Sources & evidence

ORD record
ord-58a1f283792640dfa3c733f14605665c
Source dataset
uspto-grants-1994_09
Patent number
US05348964

Reaction notes

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