Butyl vinyl ether → HCID 18469473, compound

HRID 2229892Notes

Reaction equation

CN(C)[C:3](=O)[CH3:4].Br[C:8]1[CH:9]=[C:10]([C:14]([F:17])([F:16])[F:15])[CH:11]=[CH:12][CH:13]=1.C([O:20][CH2:21][CH2:22][CH2:23][CH3:24])=C.CCCCCCCCCCCCCCCC>C(OCC)C>[F:15][C:14]([F:17])([F:16])[C:10]1[CH2:9][C:8]([O:20][CH2:21][CH2:22][CH2:23][CH3:24])([CH:13]=[CH:12][CH:11]=1)[CH:3]=[CH2:4]

Participants

Conditions

Temperature: 120 °C

Procedure

26 mg (0.025 mmol) bis-(dibenzalacetone)-chloroform-palladium and 0.1 mmol of a ligand are placed in a Schlenk-tube under argon. 4 ml N,N-dimethyl-acetamide, 1.12 g (5 mmol) 3-bromo-benzotrifluoride 0.76 g (7.5 mmol) triethyl amine and 0.75 g (7.5 mmol) butyl vinyl ether are added. The reaction mixture is heated to 120° C. for 20 hours. It is cooled to room temperature and 200 mg hexadecane (internal standard) and 15 ml diethylether are added. The mixture is analysed by GC.

Workup

temperatureIt is cooled to room temperature

Sources & evidence

ORD record: ord-b51bed7e10044564897d862afb698de2
Source dataset: uspto-grants-2002_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06420608B1

Reaction notes

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