Triphenylphosphine → HCID 18463711, compound

HRID 2231131Notes

Reaction equation

HRID 2231131 reaction equation
[CH3:1][S:2]([C:5]1[CH:12]=[CH:11][C:8]([CH2:9][Cl:10])=[CH:7][CH:6]=1)(=[O:4])=[O:3].[C:13]1([P:19]([C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)[C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>C1(C)C=CC=CC=1>[Cl-:10].[CH3:1][S:2]([C:5]1[CH:12]=[CH:11][C:8]([CH2:9][P+:19]([C:20]2[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=2)([C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)[C:13]2[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=2)=[CH:7][CH:6]=1)(=[O:4])=[O:3]

Participants

4

Reactant 2

HCID 11776TriphenylphosphineHCID 1235301-(Chloromethyl)-4-methanesulfonylbenzene

Product 1

HCID 18463711HCID 18463711, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

4-(Methylsulfonyl)benzyl chloride (Transworld Chemical) (121 mmol, 24.7 g) and triphenylphosphine (130 mmol, 34.1 g) were heated at reflux in toluene (125 ml) with stirring for 56 hours. The reaction was cooled, and the title compound was collect by filtration (48.0 g, 85%).

Workup

  1. temperatureThe reaction was cooled
  2. filtrationthe title compound was collect by filtration (48.0 g, 85%)

Sources & evidence

ORD record
ord-542d0617018c40eba1f2e177e1119482
Source dataset
uspto-grants-2002_07
Patent number
US06426360B1

Reaction notes

Loading…