Hydrogen Peroxide → N,N-ditetradecylhydroxylamine

HRID 2231348Notes

Reaction equation

HRID 2231348 reaction equation
[CH2:1]([NH:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[OH:30]O>C(O)CC>[CH2:16]([N:15]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14])[OH:30])[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 87077Dimyristylamine

Product 1

HCID 9910313N,N-ditetradecylhydroxylamine

Reagents, catalysts & solvents 1

HCID 10311-PropanolSolvent

Procedure

The general procedure of Example 12 is followed using at 50° to 55° C. 50 grams (0.12 mol) of ditetradecylamine, 200 ml of n-propanol and 8.3 grams (0.12 mol) of 50% aqueous hydrogen peroxide solution. The above-named product is obtained in a yield of 33.4 grams (64%) as white needles melting at 97°-99° C.

Workup

  1. customis followed using at 50° to 55° C

Sources & evidence

ORD record
ord-c9a1baecf861423b9e67ad80962e3047
Source dataset
uspto-grants-1988_11
Patent number
US04782105

Reaction notes

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