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HRID2236517

反应详情

EQUATION

反应方程式

HRID 2236517 的结构方程式

REACTANTS

反应物

3
结构：O=C([O-])[O-].[K+].[K+]
HCID11430

Potassium Carbonate

CK2O3

结构：O=[N+]([O-])c1ccc(CBr)cc1
HCID66011

4-Nitrobenzylbromide

C7H6BrNO2

结构：Cl.O=S1(=O)CCNCC1
HCID12324096

1lambda~6~,4-Thiazinane-1,1-dione--hydrogen chloride (1/1)

C4H10ClNO2S

PRODUCTS

生成物

1
结构：O=[N+]([O-])c1ccc(CN2CCS(=O)(=O)CC2)cc1
HCID22569762

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC#N
溶剂HCID6342

Acetonitrile

C2H3N

PROCEDURE

实验过程

To a flask containing thiomorpholine 1,1-dioxide hydrochloride (0.65 g, 3.8 mmol) in CH3CN is added 4-nitrobenzylbromide (1.1 g, 5.1 mmol) and K2CO3 (1.9 g, 13.7 mmol). The mixture is then allowed to stir at room temperature overnight. After aqueous work up, the product is obtained through chromatography. MS (ESI): 271.1 (M+1)+1

WORKUP

后处理

  1. customAfter aqueous work up, the product is obtained through chromatography