Ethanol → HCID 86737317, compound

HRID 224410Notes

Reaction equation

HRID 224410 reaction equation
[Cl:1][C:2]([CH:5]1[O:10][CH2:9][C:8]2[CH:11]=[CH:12][CH:13]=[CH:14][C:7]=2[O:6]1)([Cl:4])[Cl:3].O.[NH2:16][NH2:17].[CH2:18](O)[CH3:19]>>[C:18](=[N:16][NH2:17])([C:12]1[CH:13]=[CH:14][C:7]2[O:6][CH:5]([C:2]([Cl:1])([Cl:4])[Cl:3])[O:10][CH:9]([C:2]([Cl:4])([Cl:3])[Cl:1])[C:8]=2[CH:11]=1)[CH3:19]

Participants

4

Reactant 3

HCID 702EthanolHCID 24654Hydrazine hydrate (1:1)HCID 86737316HCID 86737316, compound

Product 1

HCID 86737317HCID 86737317, compound

Procedure

A mixture of 6-acetyl-2,4-bis(trichloromethylbenzo[1,3]dioxin (2.0 g.) and 100% hydrazine hydrate (0.25 g.) in absolute ethanol (25 ml.) was heated under reflux for 16 hours, and cooled to give 6-acetyl-2,4-bis(trichloromethyl)benzo[1,3]dioxin hydrazone, m.p. 159° C.

Workup

  1. temperaturewas heated
  2. temperatureunder reflux for 16 hours
  3. temperaturecooled

Sources & evidence

ORD record
ord-718d4b98a81f44c7aa217a7b4f3e1d28
Source dataset
uspto-grants-1980_11
Patent number
US04232032

Reaction notes

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