HCID 23333159, compound → HCID 23333169, compound

HRID 224437Notes

Reaction equation

HRID 224437 reaction equation
[CH:1]1([C:7]2[CH:16]=[CH:15][C:10]3[C:11]([CH3:14])=[CH:12][O:13][C:9]=3[CH:8]=2)[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1>C(OCC)(=O)C.[Pd]>[CH:1]1([C:7]2[CH:16]=[CH:15][C:10]3[CH:11]([CH3:14])[CH2:12][O:13][C:9]=3[CH:8]=2)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]1

Participants

4

Reactant 1

HCID 23333159HCID 23333159, compound

Product 1

HCID 23333169HCID 23333169, compound

Reagents, catalysts & solvents 2

HCID 8857Ethyl AcetateSolventHCID 23938PalladiumSolvent

Procedure

9.2 g of 6-cyclohexyl-3-methyl-benzofuran are dissolved in 140 ml of ethyl acetate and hydrogenated in the presence of palladium (10% on active charcoal). After 5 hours, the mixture is filtered and reduced in volume. 6-Cyclohexyl-2,3-dihydro-3-methyl-benzofuran is obtained as an oily product by distillation in a bulb tube at 120°/0.1 mm.

Workup

  1. filtrationthe mixture is filtered

Sources & evidence

ORD record
ord-66ed1b29850847a0b92fbfc79d211974
Source dataset
uspto-grants-1980_11
Patent number
US04232039

Reaction notes

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