Methyldichlorosilane → HCID 123155376, compound

HRID 2249930Notes

Reaction equation

HRID 2249930 reaction equation
[CH2:1]1[CH:5]2[CH:6]3C=CC([CH:4]2[CH:3]=[CH:2]1)C3.C[SiH:12]([Cl:14])[Cl:13].CCCCCCCCCCCCCCCC>[Pd](Cl)Cl.C1(P(C2C=CC=CC=2)CCCCP(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.C1(C)C=CC=CC=1>[CH:5]1([CH2:6][SiH:12]([Cl:14])[Cl:13])[CH2:4][CH2:3][CH:2]=[CH:1]1

Participants

7

Reactant 3

HCID 6376MethyldichlorosilaneHCID 6492DicyclopentadieneHCID 11006Hexadecane

Product 1

HCID 123155376HCID 123155376, compoundYield 337.4%

Reagents, catalysts & solvents 3

HCID 24290Palladium ChlorideCatalystHCID 821241,4-Bis(diphenylphosphino)butaneCatalystHCID 1140TolueneSolvent

Procedure

As described in Example 2, 2.85 g (0.0216 mol) of dicyclopentadiene, 3.72 g (0.0323 mol) of methyldichlorosilane, 0.040 g (0.000226 mol) of palladium dichloride, 0.19 g (0.000451 mol) of 1,4-bis(diphenylphosphino)butane and 4 mL of toluene and 2 mL of hexadecane were placed in a reactor. The reactor was sealed and the reaction was performed at 180° C. for 2 hours. Products were subject to simple vacuum distillation, thereby providing a mixture (13.2 g) of (2-cyclopentenyl)methyldichlorosilane (4.1 g, 70%), other unreacted reactants, toluene, hexadecane, and unidentified compounds.

Workup

  1. customwere placed in a reactor
  2. customThe reactor was sealed
  3. distillationProducts were subject to simple vacuum distillation

Sources & evidence

ORD record
ord-8567662017c045a1b28e925758c8e17f
Source dataset
uspto-grants-2008_01
Patent number
US07314946B2

Reaction notes

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