Potassium Carbonate → Undecane

HRID 2255706Notes

Reaction equation

HRID 2255706 reaction equation
[CH3:1][CH2:2][CH2:3][CH:4](C([O-])=O)[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].C(=O)([O-])[O-].[K+].[K+]>Cl>[CH3:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

Participants

4

Reactant 2

HCID 11430Potassium CarbonateHCID 19738510HCID 19738510, compound

Product 1

HCID 14257Undecane

Reagents, catalysts & solvents 1

HCID 313Hydrochloric AcidSolvent

Procedure

9 g (40 mmol) of ethyl 1,4-diazatircylco[6.2.0.02,6 ]undecane-4-carboxylate are heated under reflux overnight with 50 ml of concentrated hydrochloric acid. The mixture is rendered alkaline with potassium carbonate and extracted ten times using 50 ml of chloroform each time, the extracts are dried over potassium carbonate and concentrated, and the residue is distilled.

Workup

  1. extractionextracted ten times
  2. dry with materialthe extracts are dried over potassium carbonate
  3. concentrationconcentrated
  4. distillationthe residue is distilled

Sources & evidence

ORD record
ord-956372b18c4249309191671b579b2207
Source dataset
uspto-grants-1993_08
Patent number
US05241076

Reaction notes

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